Participants
| Role | Name | HCID | Charge |
|---|
| Reactant | Styrene | HCID 7501 | — |
| Reactant | Chlorobenzene | HCID 7964 | — |
| Product | 1,1-Diphenylethylene | HCID 10740 | 12.4% |
| Product | trans-Stilbene | HCID 638088 | 86.7% |
| Product | cis-Stilbene | HCID 5356785 | 0.9% |
Reaction Steps
A reaction is performed as described in Example 1, except that 102.8 mg (0.99 mmol) of styrene and 164.8 mg (1.46 mmol) of chlorobenzene are used, and the reaction mixture is stirred at 150° C. for 5.5 hours. With 94.6% conversion of Cl-benzene, an 82.1% yield of Heck products (86.7% trans-stilbene, 0.9% cis-stilbene, 12.4% 1,1-diphenylethene) is obtained.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|
| Patent number | US06316675B1 |
|---|
| Source dataset | uspto-grants-2001_11 |
|---|
| ORD ID | ord-0f3dd49aeb5e4d00b6d810eb17ec34cb |
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| Source note | uspto-grants-2001_11 |
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