Bromotriphenylmethane → 1-Iodo-3-triphenylmethoxy-trans-1-octene

HRID 436097

Reaction equation

HRID 436097 reaction equation
[I:1]/[CH:2]=[CH:3]/[CH:4]([OH:10])[CH2:5][CH2:6][CH2:7][CH2:8][CH3:9].[C:11]1([C:17](Br)([C:24]2[CH:29]=[CH:28][CH:27]=[CH:26][CH:25]=2)[C:18]2[CH:23]=[CH:22][CH:21]=[CH:20][CH:19]=2)[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1>N1C=CC=CC=1>[I:1]/[CH:2]=[CH:3]/[CH:4]([O:10][C:17]([C:11]1[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=1)([C:24]1[CH:25]=[CH:26][CH:27]=[CH:28][CH:29]=1)[C:18]1[CH:19]=[CH:20][CH:21]=[CH:22][CH:23]=1)[CH2:5][CH2:6][CH2:7][CH2:8][CH3:9]

Participants

4

Reactant 2

HCID 11692BromotriphenylmethaneHCID 110432831-Iodo-trans-1-octene-3-ol

Product 1

HCID 201446361-Iodo-3-triphenylmethoxy-trans-1-octene

Reagents, catalysts & solvents 1

HCID 1049PyridineSolvent

Procedure

Treatment of 7.62 g. (0.03 mole) of 1-iodo-trans-1-octen-3-ol with 10.67 g. (0.033 mole) of triphenylmethyl bromide in pyridine in the manner described in Example 728 gave 13.448 g. (90%) of a colorless oil.

Workup

  1. customgave 13.448 g

Sources & evidence

ORD record
ord-270bf30cc99540d9a8ce1ed7640f2e46
Source dataset
uspto-grants-1977_02
Patent number
US04007210

Linked notes

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