Potassium bisulfide → Potassium p-chlorophenoxymethyldithiocarbamate

HRID 436628

Reaction equation

HRID 436628 reaction equation
[Cl:1][C:2]1[CH:12]=[CH:11][C:5]([O:6][CH2:7][N:8]=[C:9]=[S:10])=[CH:4][CH:3]=1.[SH-:13].[K+:14]>C(O)(C)(C)C.CC(C)=O>[Cl:1][C:2]1[CH:3]=[CH:4][C:5]([O:6][CH2:7][NH:8][C:9](=[S:13])[S-:10])=[CH:11][CH:12]=1.[K+:14]

Participants

5

Reactant 2

HCID 102109Potassium bisulfideHCID 21453287p-Chlorophenoxymethyl isothiocyanate

Product 1

HCID 23667330Potassium p-chlorophenoxymethyldithiocarbamate

Reagents, catalysts & solvents 2

HCID 180AcetoneSolventHCID 6386tert-ButanolSolvent

Procedure

Potassium p-chlorophenoxymethyldithiocarbamate was prepared by the reaction of p-chlorophenoxymethyl isothiocyanate with potassium hydrosulfide in a mixture of t-butyl alcohol and acetone.

Sources & evidence

ORD record
ord-c1c364444a3d473eae2da6d38caceffe
Source dataset
uspto-grants-1977_02
Patent number
US04009279

Linked notes

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