Oxygen → Diphenylformamide

HRID 441784

Reaction equation

HRID 441784 reaction equation
[CH3:1][N:2]([C:9]1[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1)[C:3]1[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=1.[O:15]=O>>[C:9]1([N:2]([C:3]2[CH:8]=[CH:7][CH:6]=[CH:5][CH:4]=2)[CH:1]=[O:15])[CH:14]=[CH:13][CH:12]=[CH:11][CH:10]=1

Participants

3

Reactant 2

HCID 977OxygenHCID 11098Methyldiphenylamine2×

Product 1

HCID 69081DiphenylformamideYield 43.3%

Procedure

By essentially the procedure of Example 1, a tube was charged with 40 g of methyldiphenylamine and 2.0 g CuCl2. 2H2O. The reaction was run at 115°-125° C. for 2 hr at 290-400 psi. About 0.1 mole of oxygen was injected incrementally. GC/MS analysis showed a 98.6% conversion of methyldiphenylamine and a 43.3% yield of diphenylformamide.

Sources & evidence

ORD record
ord-9030a9fdf81e4b68b1daa6a663d70bb7
Source dataset
uspto-grants-1977_08
Patent number
US04042621

Linked notes

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