Phosphorus → Phenyl benzoate

HRID 443084

Reaction equation

HRID 443084 reaction equation
[C:1]1([C:7](=O)[C:8]([O:10][C:11]2[CH:16]=[CH:15][CH:14]=[CH:13][CH:12]=2)=[O:9])[CH:6]=[CH:5][CH:4]=[CH:3]C=1.[P]>C(Cl)(Cl)Cl>[C:8]([O:10][C:11]1[CH:12]=[CH:13][CH:14]=[CH:15][CH:16]=1)(=[O:9])[C:7]1[CH:3]=[CH:4][CH:5]=[CH:6][CH:1]=1

Participants

4

Reactant 2

HCID 5462309PhosphorusHCID 13975017Phenyl phenylglyoxylate

Product 1

HCID 7169Phenyl benzoate

Reagents, catalysts & solvents 1

HCID 6212ChloroformSolvent

Procedure

The decarbonylation reaction of phenyl phenylglyoxylate (PPG) was repeated in the manner as described in Example 79, except that the organic phosphorus compound set forth in Table 12 was employed and the amount of chloroform was changed as set forth in Table 12. The results are also set forth in Table 12.

Sources & evidence

ORD record
ord-f7fbf6f2a6444ceea29bd3e415ab91da
Source dataset
uspto-grants-1999_04
Patent number
US05892091

Linked notes

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