2-Tridecanone oxime → 2-Aminotridecane

HRID 444250Notes

Reaction equation

HRID 444250 reaction equation
[CH3:1][C:2](=[N:14]O)[CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13]>[Pd].C(O)C>[NH2:14][CH:2]([CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH3:13])[CH3:1]

Participants

4

Reactant 1

HCID 740543132-Tridecanone oxime

Product 1

HCID 1232972-AminotridecaneYield 85.6%

Reagents, catalysts & solvents 2

HCID 23938PalladiumCatalystHCID 702EthanolSolvent

Procedure

20 g of 2-tridecanone oxime are reduced in 200 ml of abs. ethanol with 2 g of 5% palladium on charcoal, affording 16 g of 2-aminotridecane. Boiling point: 82°-87° C./0.01.

Sources & evidence

ORD record
ord-e58b3ba937c7401eae2f4d79ba813ad9
Source dataset
uspto-grants-1981_04
Patent number
US04263324

Reaction notes

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