1,2-Phenanthrenedione → 10-(Trifluoromethyl)dibenzo[a,c]phenazine

HRID 461665

Reaction equation

HRID 461665 reaction equation
[NH2:1][C:2]1[C:7]([N+:8]([O-])=O)=[CH:6][CH:5]=[CH:4][C:3]=1[C:11]([F:14])([F:13])[F:12].[C:15]1(=O)[C:28]2[CH:27]=[CH:26][C:25]3[C:20](=[CH:21][CH:22]=[CH:23][CH:24]=3)[C:19]=2[CH:18]=[CH:17][C:16]1=O>>[F:12][C:11]([F:14])([F:13])[C:3]1[CH:4]=[CH:5][CH:6]=[C:7]2[C:2]=1[N:1]=[C:26]1[C:27](=[N:8]2)[C:28]2[CH:15]=[CH:16][CH:17]=[CH:18][C:19]=2[C:20]2[CH:21]=[CH:22][CH:23]=[CH:24][C:25]1=2

Participants

3

Reactant 2

HCID 30805661,2-PhenanthrenedioneHCID 107034572-Amino-3-nitrobenzotrifluoride

Product 1

HCID 2139172710-(Trifluoromethyl)dibenzo[a,c]phenazineYield 76%

Procedure

When 0.034 mole each of 2-amino-3-nitrobenzotrifluoride and phenanthrenequinone were reacted by the method of Example 1, 9 g. (76 percent yield) of 10-(trifluoromethyl)dibenzo[a,c]phenazine, mp = 195°-196° C., were obtained.

Sources & evidence

ORD record
ord-611cd63d36094e349c11311cfe3718ee
Source dataset
uspto-grants-1977_12
Patent number
US04064127

Linked notes

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