HuagongsheHuagongshe Chemistry Print Report · For research reference only
Water → 2,7-Bis[4-(3-azabicyclo[3.2.2]nonan-3-yl)butyryl]fluorene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Water | HCID 962 | — |
| Reactant | Potassium Iodide | HCID 4875 | — |
| Reactant | 3-Azabicyclo[3.2.2]nonane | HCID 9240 | — |
| Reactant | 1,1'-(9H-Fluorene-2,7-diyl)bis(4-chlorobutan-1-one) | HCID 13170549 | — |
| Solvent | Methyl Ethyl Ketone | HCID 6569 | — |
| Product | 2,7-Bis[4-(3-azabicyclo[3.2.2]nonan-3-yl)butyryl]fluorene | HCID 21392969 | — |
Reaction Steps
A mixture of 11.25g (0.03 mole) of 2,7-bis(4-chlorobutyryl)fluorene, 30.1g (0.24 mole) of 3-azabicyclo[3.2.2]nonane and 10.0g (0.06 mole) of potassium iodide in 200 ml butanone is heated at reflux with stirring for 3 days. The reaction mixture was poured into 1000 ml of water, and the resulting solid precipitate filtered and recrystallized from chloroform-acetone to yield the desired product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04064347 |
| Source dataset | uspto-grants-1977_12 |
| ORD ID | ord-8473c2850e8a4a778bc52f25ae3b2d26 |
| Source note | uspto-grants-1977_12 |