HuagongsheHuagongshe Chemistry Print Report · For research reference only
4-Chloro-1,2-dinitrobenzene → ethyl P-methyl-2-nitro-5-chlorophenylphosphinate
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 4-Chloro-1,2-dinitrobenzene | HCID 33097 | — |
| Reactant | Diethyl methylphosphonite | HCID 85063 | — |
| Solvent | Acetonitrile | HCID 6342 | — |
| Product | ethyl P-methyl-2-nitro-5-chlorophenylphosphinate | HCID 53860251 | — |
Reaction Steps
A mixture of 4-chloro-1,2-dinitrobenzene (3.31 mmol) and diethyl methylphosphonite (5.30 mmol) in 3 ml of acetonitrile is stirred at RT overnight. The mixture is then concentrated and the residue is purified by preparative TLC to yield ethyl P-methyl-2-nitro-5-chlorophenylphosphinate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04520197 |
| Source dataset | uspto-grants-1985_05 |
| ORD ID | ord-d946924498814018b352a39df226c1bf |
| Source note | uspto-grants-1985_05 |