(Z)-dodec-7-enol → 11-Tetradecen-1-ol, (11E)-

HRID 463639

Reaction equation

HRID 463639 reaction equation
FC(O)CCCCCCCCCCC.C(O)CCCCC/C=C\CCCC.C(O)CCCCCCC/C=C\CC.[CH2:41]([OH:55])[CH2:42][CH2:43][CH2:44]/[CH:45]=[CH:46]\[CH2:47][CH2:48][CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH3:54]>>[CH2:41]([OH:55])[CH2:42][CH2:43][CH2:44][CH2:45][CH2:46]/[CH:47]=[CH:48]\[CH2:49][CH2:50][CH2:51][CH2:52][CH2:53][CH3:54].[CH2:41]([OH:55])[CH2:42][CH2:43][CH2:44][CH2:45][CH2:46][CH2:47][CH2:48][CH2:49][CH2:50]/[CH:51]=[CH:52]/[CH2:53][CH3:54]

Participants

6

Reactant 4

HCID 5362794(Z)-dodec-7-enolHCID 6427104(Z)-tetradec-5-en-1-olHCID 64313429-Dodecen-1-ol, (9Z)-HCID 220004641-Fluorododecanol

Product 2

HCID 171201111-Tetradecen-1-ol, (11E)-HCID 5362795cis-7-Tetradecenol

Procedure

In accordance with the foregoing procedures but where, in place of 1-fluorododecanol there is utilized (Z)-7-dodecenol; (Z)-9-dodecenol; (Z)-5-tetradecenol; (Z)-7-tetradecenol or (E)-11-tetradecenol there are obtained the corresponding (Z)-7-dodecenoic, (Z)-9-dodecenoic, (Z)-5-tetradecenoic, (Z)-7-tetradecenoic, (Z)-11-tetradecenoic or (E)-11-tetradecenoic acids respectively.

Sources & evidence

ORD record
ord-4bcb45c64626469ab64cf0f5b9212be9
Source dataset
uspto-grants-1985_10
Patent number
US04544504

Linked notes

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