Methyl nadic anhydride → Epoxy-styrene

HRID 46462

Reaction equation

HRID 46462 reaction equation
C[C:2]12[CH:8]3[C:9]([O:11][C:12](=O)[CH:7]3[CH:4]([CH:5]=[CH:6]1)C2)=O>CC(OOC(=O)C1C=CC=CC=1)(CCC(C)(OOC(=O)C1C=CC=CC=1)C)C>[O:11]1[C:12]([C:7]2[CH:4]=[CH:5][CH:6]=[CH:2][CH:8]=2)=[CH:9]1

Participants

3

Reactant 1

HCID 32802Methyl nadic anhydride

Product 1

HCID 14299145Epoxy-styrene

Reagents, catalysts & solvents 1

HCID 757962,5-Dimethyl-2,5-DI-(benzoylperoxy)hexaneCatalyst

Procedure

To this inhibited epoxy diester-styrene mixture 5.49 parts of NADIC methyl anhydride and 0.048 part of 2,5-dimethyl-2,5 bis(benzoyl peroxy) hexane catalyst (sold by Wallace & Tiernan Inc. under the trade name of Luperox 118) were added, at 25° C., to provide the solventless epoxy-styrene impregnating varnish. The catalyst used has a catalytic reaction "kick off" temperature of about 115° C., i.e., it will have a definite catalytic effect to initiate a cure reaction at over about 115° C. The viscosity of the epoxy-styrene impregnating varnish was measured to be about 10 cps to 15 cps at 25° C. To this resin system 0.029 part of various metal acetylacetonates were added. One sample, containing no metal acetylacetonate was used as a control. The weight ratio of epoxy mixture: styrene: metal acetylacetonate was 1:1.9:0.0029. This varnish was prepared in 1 gallon laboratory batches and in 250 gallon large scale commercial batches.

Workup

  1. additionunder the trade name of Luperox 118) were added, at 25° C.

Sources & evidence

ORD record
ord-74e2baf889884f59b7c28b7669ce62c6
Source dataset
uspto-grants-1979_11
Patent number
US04173593

Linked notes

Loading…