Dipotassium tetrachloroplatinate → dichloroplatinum;4,5-dihydro-1H-imidazol-2-ylhydrazine
Reaction equation
[Cl:1][Pt-2:2](Cl)(Cl)[Cl:3].[K+].[K+].[NH:8]([C:10]1[NH:11][CH2:12][CH2:13][N:14]=1)[NH2:9].C([O-])(=O)C.[Na+]>O>[Pt:2]([Cl:3])[Cl:1].[NH:8]([C:10]1[NH:14][CH2:13][CH2:12][N:11]=1)[NH2:9]Participants
5
Reactant 3
Product 1
Reagents, catalysts & solvents 1
Procedure
To a solution of 4.16 g of potassium tetrachloroplatinate in 15 ml of water was added a 15 ml aqueous solution containing 1.37 g of 2-hydrazino-4,5-dihydro-1H-imidazole and 0.82 g of sodium acetate. The mixture was allowed to stand at room temperature for 24 hours to give the desired complex as light brown crystals mp>290° C.
Sources & evidence
- ORD record
- ord-397260ad157c48af9ab82b33541deb11
- Source dataset
- uspto-grants-1985_10
- Patent number
- US04550169
Reaction notes
Loading…