HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cyclohexanone → 8-(2-Methyl-3-buten-2-ylperoxy)-p-menthane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cyclohexanone | HCID 7967 | — |
| Reactant | 2,5-Hexanedione | HCID 8035 | — |
| Reactant | Cyclopentanone | HCID 8452 | — |
| Reactant | Cyclododecanone | HCID 13246 | — |
| Reactant | 3,3,5-Trimethylcyclohexanone | HCID 13398 | — |
| Reactant | Butyl levulinate | HCID 16331 | — |
| Reactant | Methoxyacetone | HCID 22172 | — |
| Solvent | Acetone | HCID 180 | — |
| Solvent | Methyl Ethyl Ketone | HCID 6569 | — |
| Solvent | Ethyl ketone | HCID 7288 | — |
| Solvent | Methyl Isobutyl Ketone | HCID 7909 | — |
| Product | 8-(2-Methyl-3-buten-2-ylperoxy)-p-menthane | HCID 19814568 | — |
Reaction Steps
In the preparation of the present diperoxy ketals a t-alkenyl hydroperoxide (II) can be reacted in a usual way with a ketone in an acid medium. As examples of suitable ketones may be mentioned: acetone, methoxyacetone, methyl ethyl ketone, diethyl ketone, methyl isobutyl ketone, n-butyl-4-ketovalerate, 2,5-hexanedione, cyclohexanone, 3,3,5-trimethylcyclohexanone, cyclopentanone and cyclododecanone.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05157087 |
| Source dataset | uspto-grants-1992_10 |
| ORD ID | ord-89e63318b7bd4baca3d4365ec665e90f |
| Source note | uspto-grants-1992_10 |