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Sodium Hydroxide → Zinc Dodecyl Fumarate

HRID 467172
Notes
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Reaction equation

HRID 467172 reaction equation
[C:1]([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])(=[O:7])/[CH:2]=[CH:3]/[C:4]([O-:6])=[O:5].[OH-].[Na+].O.O.C([O-])(=O)C.[Zn+2:29].C([O-])(=O)C>CC(C)=O>[C:1]([O:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20])(=[O:7])/[CH:2]=[CH:3]/[C:4]([O-:6])=[O:5].[Zn+2:29].[CH2:9]([O:8][C:1](=[O:7])/[CH:2]=[CH:3]/[C:4]([O-:6])=[O:5])[CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH3:20]
ParticipantsConditionsProcedureWorkupSources & evidenceReaction notes

Participants

5

Reactant 3

HCID 14798Sodium HydroxideHCID 2724192Zinc acetate (USP)HCID 22320807HCID 22320807, compound

Product 1

HCID 86744016Zinc Dodecyl Fumarate

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Conditions

Temperature
50 °C

Procedure

To a 12 percent w/v acetone suspension of the monododecyl fumarate heated to 50° C. is added 1.0 molar equivalent sodium hydroxide (299 g) as a 10 percent w/v aqueous solution. After the stirred suspension clears, 0.5 molar equivalent zinc acetate dihydrate (110 g) as a saturated aqueous solution is added with stirring. The supernatant liquid is separated from the precipitated zinc dodecyl fumarate.

Workup

  1. customThe supernatant liquid is separated from the precipitated zinc dodecyl fumarate

Sources & evidence

ORD record
ord-29b36aba3d78430aa57992e2f662b67b
Source dataset
uspto-grants-1992_10
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US05159035

Reaction notes

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On this pageParticipantsConditionsProcedureWorkupSources & evidenceReaction notes