Methoxymethylbutanol → 2-(3-Methoxy-3-methylbutoxy)-6-nitrobenzonitrile

HRID 471698

Reaction equation

[CH3:1][O:2][C:3]([CH3:8])([CH3:7])[CH2:4][CH2:5][OH:6].[N+:9]([C:12]1[CH:19]=[CH:18][CH:17]=[C:16]([N+]([O-])=O)[C:13]=1[C:14]#[N:15])([O-:11])=[O:10]>>[CH3:1][O:2][C:3]([CH3:8])([CH3:7])[CH2:4][CH2:5][O:6][C:16]1[CH:17]=[CH:18][CH:19]=[C:12]([N+:9]([O-:11])=[O:10])[C:13]=1[C:14]#[N:15]

Participants

Reactant 2

HCID 62118Methoxymethylbutanol

HCID 520718Dinitrobenzonitrile

Product 1

HCID 674011512-(3-Methoxy-3-methylbutoxy)-6-nitrobenzonitrileYield 52%

Procedure

Prepared as in Example 215c from 3-methoxy-3-methylbutan-1-ol and 2,6-dinitrobenzonitrile in 52% yield. MS 265 (MH+).

Sources & evidence

ORD record: ord-4f75fd2ca6b24187b86c979287659b75
Source dataset: uspto-grants-2014_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08633186B2

Linked notes

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