Dinitrobenzonitrile → HCID 66747095, compound

Reaction equation

[OH:1][CH2:2][C:3]([NH:6][C:7](=[O:11])[CH2:8][CH2:9][CH3:10])([CH3:5])[CH3:4].[N+:12]([C:15]1[CH:22]=[CH:21][CH:20]=[C:19]([N+]([O-])=O)[C:16]=1[C:17]#[N:18])([O-:14])=[O:13]>>[C:17]([C:16]1[C:15]([N+:12]([O-:14])=[O:13])=[CH:22][CH:21]=[CH:20][C:19]=1[O:1][CH2:2][C:3]([NH:6][C:7](=[O:11])[CH2:8][CH2:9][CH3:10])([CH3:5])[CH3:4])#[N:18]

Participants

Reactant 2

HCID 520718Dinitrobenzonitrile

HCID 12497727N-(1-hydroxy-2-methylpropan-2-yl)butyramide

Product 1

HCID 66747095HCID 66747095, compoundYield 72%

Procedure

Prepared as in Example 215c from N-(1-hydroxy-2-methylpropan-2-yl)butyramide (Example 229d) and 2,6-dinitrobenzonitrile in 72% yield. MS 306 (MH+).

Sources & evidence

ORD record: ord-c60307f98a5242b2936c41bc55a7d13b
Source dataset: uspto-grants-2014_01
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08633186B2

Reaction notes

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