HuagongsheHuagongshe Chemistry Print Report · For research reference only
Cyclohexanone, 2-hydroxy- → 3-Methyl-4,6,7,8-tetrahydro-2(3H)-naphthalenone
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Cyclohexanone, 2-hydroxy- | HCID 10785 | — |
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | 1-Penten-3-one | HCID 15394 | — |
| Reactant | Lithium diisopropylamide | HCID 2724682 | — |
| Reactant | 2,3-Dimethyl-2-cyclohexen-1-one | HCID 10887898 | — |
| Solvent | Methanol | HCID 887 | — |
| Solvent | Tetrahydrofuran | HCID 8028 | — |
| Product | 3-Methyl-4,6,7,8-tetrahydro-2(3H)-naphthalenone | HCID 10909881 | — |
Reaction Steps
This material is prepared according to the procedure for Preparation 5 wherein 2-hydroxycyclohexanone is substituted for 2,3-dimethylcyclohexenone, methylbutenone is substituted for MVK, and 2N KOH in MeOH is substituted fro LDA in THF.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04889947 |
| Source dataset | uspto-grants-1989_12 |
| ORD ID | ord-ace3d167981649f5b92a1c86044c0fb5 |
| Source note | uspto-grants-1989_12 |