2,6-Dimethyl-4-nitroaniline → 2-[(2,6-Dimethyl-4-nitrophenyl)amino]-1-pyrroline

HRID 484787

Reaction equation

HRID 484787 reaction equation
Cl[C:2]1[CH2:6][CH2:5][CH2:4][N:3]=1.[CH3:7][C:8]1[CH:14]=[C:13]([N+:15]([O-:17])=[O:16])[CH:12]=[C:11]([CH3:18])[C:9]=1[NH2:10]>>[CH3:7][C:8]1[CH:14]=[C:13]([N+:15]([O-:17])=[O:16])[CH:12]=[C:11]([CH3:18])[C:9]=1[NH:10][C:2]1[CH2:6][CH2:5][CH2:4][N:3]=1

Participants

3

Reactant 2

HCID 281592,6-Dimethyl-4-nitroanilineHCID 135201412-Chloro-1-pyrroline

Product 1

HCID 202723942-[(2,6-Dimethyl-4-nitrophenyl)amino]-1-pyrroline

Procedure

A mixture of 2-chloro-1-pyrroline, prepared as in Example 1, and 19.9 g (0.12 mole) of the aniline product of Example 6 were heated at reflux overnight, according to the general method of Example 8. The title compound was isolated and used for subsequent reactions without further purification. Structure assignment was supported by nmr and infrared spectra.

Workup

  1. temperaturewere heated
  2. temperatureat reflux overnight

Sources & evidence

ORD record
ord-b73808b27f264206b52ae5c5d7b1945f
Source dataset
uspto-grants-1985_08
Patent number
US04533739

Linked notes

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