HuagongsheHuagongshe Chemistry Print Report · For research reference only
Camphor → Bornylene
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Camphor | HCID 2537 | — |
| Reactant | HCID 178418348 | HCID 178418348 | — |
| Solvent | Diethyl Ether | HCID 3283 | — |
| Product | Bornylene | HCID 10047 | — |
Reaction Steps
1,7,7-Trimethylbicyclo[2.2.1]heptan-2-one (1-camphor) was converted into its 4-toluenesulfonylhydrazone, which was then reacted with methyllithium in ether, to give the title compound. The method used was that described by Shapiro and Duncan, Organic Synthesis, Vol 51, pp 67-69, for the conversion of racemic camphor into racemic 1,7,7-trimethylbicyclo[2.2.1]hept-2-ene.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05242911 |
| Source dataset | uspto-grants-1993_09 |
| ORD ID | ord-58c68fbf10174a44867b9854715d2022 |
| Source note | uspto-grants-1993_09 |