2-Propylhept-2-enal → 2-Propylheptanal

HRID 522251

Reaction equation

HRID 522251 reaction equation
[CH2:1]([C:4](=[CH:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH:5]=[O:6])[CH2:2][CH3:3]>[Pd].[C]>[CH2:1]([CH:4]([CH2:7][CH2:8][CH2:9][CH2:10][CH3:11])[CH:5]=[O:6])[CH2:2][CH3:3]

Participants

3

Reactant 1

HCID 1187452-Propylhept-2-enal

Product 1

HCID 30186342-PropylheptanalYield 97.8%

Reagents, catalysts & solvents 1

HCID 178418390HCID 178418390, compoundCatalyst

Conditions

Temperature
75 °C

Procedure

An autoclave was charged with 420 g of 2-propyl-2-heptenal and 4 g of a 5% Pd carbon powder (water content: 56%, manufactured by N.E. Chemcat Corporation), and the mixture was stirred at 75° C. for 1.5 hours under a hydrogen pressure of 1.5 MPa. The reaction product was filtered through a membrane filter (PTFE, 0.5 μm) to obtain 416 g of 2-propylheptanal.

Workup

  1. filtrationThe reaction product was filtered through a membrane
  2. filtrationfilter (PTFE, 0.5 μm)

Sources & evidence

ORD record
ord-f577967a37614483969cbe2e27e6788d
Source dataset
uspto-grants-2016_05
Patent number
US09328306B2

Linked notes

Loading…