Cyclohexanone → 1-Hydroxycyclohexyl phenyl ketone

HRID 529437

Reaction equation

HRID 529437 reaction equation
[C:1]1(=[O:7])[CH2:6][CH2:5][CH2:4][CH2:3][CH2:2]1.[C:8]1(=O)[O:14][CH2:13][CH2:12][CH2:11][CH2:10][CH2:9]1.[C:16]([O-])(=O)C=C>C(C(C)=O)C>[CH2:4]1[CH2:5][CH2:6][C:1]([OH:7])([C:13]([C:12]2[CH:11]=[CH:10][CH:9]=[CH:8][CH:16]=2)=[O:14])[CH2:2][CH2:3]1

Participants

5

Reactant 3

HCID 7967CyclohexanoneHCID 10401epsilon-CAPROLACTONEHCID 25188Acrylate

Product 1

HCID 703551-Hydroxycyclohexyl phenyl ketone

Reagents, catalysts & solvents 1

HCID 6569Methyl Ethyl KetoneSolvent

Procedure

To 900 parts by weight of methyl ethyl ketone were added 100 parts by weight of cyclohexanone, 750 parts by weight of partially caprolactone-modified polyfunctional acrylate (DPCA-20, produced by Nippon Kayaku Co., Ltd.), 200 parts by weight of a silica sol (MIBK-ST, produced by Nissan Chemical Industries, Ltd.) and 50 parts by weight of a photopolymerization initiator (IRGACURE 184, produced by Ciba Specialty Chemicals Corp.), followed by stirring. The mixture was filtered through a polypropylene filter having a pore size of 0.4 μm to prepare Coating solution A for hardcoat layer.

Sources & evidence

ORD record
ord-9a57fa932ad648018dd025c593e3007b
Source dataset
uspto-grants-2016_05
Patent number
US09346961B2

Linked notes

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