4-Pentenoic acid, phenylmethyl ester → HCID 90418027, compound

HRID 530136

Reaction equation

HRID 530136 reaction equation
[Cl:1][SiH:2]1[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1.[C:8]([O:14][CH2:15][C:16]1[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=1)(=[O:13])[CH2:9][CH2:10][CH:11]=[CH2:12]>>[Cl:1][Si:2]1([CH2:12][CH2:11][CH2:10][CH2:9][C:8]([O:14][CH2:15][C:16]2[CH:21]=[CH:20][CH:19]=[CH:18][CH:17]=2)=[O:13])[CH2:7][CH2:6][CH2:5][CH2:4][CH2:3]1

Participants

3

Reactant 2

HCID 100520354-Pentenoic acid, phenylmethyl esterHCID 713532331-Chlorosilinane

Product 1

HCID 90418027HCID 90418027, compound

Conditions

Temperature
60 °C

Procedure

To a mixture of crude 1-chlorosilinane (0.35 g) and benzyl pent-4-enoate (0.50 g; 2.63 mmol) under argon was added two drops of Karstedt's catalyst solution (in xylenes; ˜2% Pt). The reaction vessel was sealed and the mixture was heated to 60° C. for 16 hours. The crude liquid was used without purification.

Workup

  1. customThe reaction vessel was sealed
  2. customThe crude liquid was used without purification

Sources & evidence

ORD record
ord-5d833aab1b014d648e7249199a29c9a5
Source dataset
uspto-grants-2016_05
Patent number
US09352049B2

Linked notes

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