4-Pentenoic acid, phenylmethyl ester → HCID 90417926, compound

HRID 530137

Reaction equation

HRID 530137 reaction equation
[Cl:1][SiH:2]1[CH2:6][CH2:5][CH2:4][CH2:3]1.[C:7]([O:13][CH2:14][C:15]1[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=1)(=[O:12])[CH2:8][CH2:9][CH:10]=[CH2:11]>>[Cl:1][Si:2]1([CH2:11][CH2:10][CH2:9][CH2:8][C:7]([O:13][CH2:14][C:15]2[CH:20]=[CH:19][CH:18]=[CH:17][CH:16]=2)=[O:12])[CH2:6][CH2:5][CH2:4][CH2:3]1

Participants

3

Reactant 2

HCID 100520354-Pentenoic acid, phenylmethyl esterHCID 713641681-Chlorosilolane

Product 1

HCID 90417926HCID 90417926, compound

Conditions

Temperature
60 °C

Procedure

To a mixture of crude 1-chlorosilolane (0.317 g) and benzyl pent-4-enoate (0.50 g; 2.63 mmol) under argon was added two drops of Karstedt's catalyst solution (in xylenes; ˜2% Pt). The reaction vessel was sealed and the mixture was heated to 60° C. for 18 hours. The crude liquid was used without purification.

Workup

  1. customThe reaction vessel was sealed
  2. customThe crude liquid was used without purification

Sources & evidence

ORD record
ord-822de5eb39cf41d8a61145a148ccab26
Source dataset
uspto-grants-2016_05
Patent number
US09352049B2

Linked notes

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