HuagongsheHuagongshe Chemistry Print Report · For research reference only
alpha-Thujene → 2-Methyl-5-(1-methylethyl)bicyclo(3.1.0)hexan-2-ol
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | alpha-Thujene | HCID 17868 | — |
| Reactant | Perhydroxyl radical | HCID 18500 | — |
| Catalyst | Nickel | HCID 935 | — |
| Product | 2-Methyl-5-(1-methylethyl)bicyclo(3.1.0)hexan-2-ol | HCID 62367 | — |
Reaction Steps
The hydroperoxide resulting from α-thujene can be reduced to 4-hydroxy-β-thujene and can then be hydrogenated, e.g. in the presence of Raney nickel, to give sabinene hydrate.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05620569 |
| Source dataset | uspto-grants-1997_04 |
| ORD ID | ord-c8171cd5fd0b4c1a9e57d3f8d8be06ad |
| Source note | uspto-grants-1997_04 |