TIBA isododecane → 2,3,5-Triiodobenzoic acid

HRID 549509

Reaction equation

HRID 549509 reaction equation
[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12].CCCCCCCCCC(C)C>C1(C)C=CC=CC=1>[CH:1]1[C:6]([I:7])=[C:5]([I:8])[C:4]([C:9]([OH:11])=[O:10])=[CH:3][C:2]=1[I:12]

Participants

3

Reactant 1

HCID 131728349TIBA isododecane

Product 1

HCID 69482,3,5-Triiodobenzoic acid

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

33.3 ml of TIBA/isododecane solution (101 g/L) was mixed with 7.9 cc of MAO/toluene solution (Albemarle −30% wt) to obtain a MAO/TIBA molar ratio of 2:1. The solution was stirred for 1 hour at room temperature. Then, 69 mg of A-1 was dissolved in the solution.

Sources & evidence

ORD record
ord-7c8ef107c3634e86a66b5e20aa7b8cba
Source dataset
uspto-grants-2011_05
Patent number
US07943716B2

Linked notes

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