Methyl 4-allyl-3-hydroxyoctanoate → Methyl 3-hydroxy-2-isobutyl-6-heptenoate

HRID 551640

Reaction equation

HRID 551640 reaction equation
C([CH:4]([CH2:12][CH2:13][CH2:14]C)[CH:5]([OH:11])[CH2:6][C:7]([O:9][CH3:10])=[O:8])C=C.[CH2:16](C(CC=C)C=O)[CH:17]([CH3:19])[CH3:18]>>[OH:11][CH:5]([CH2:4][CH2:12][CH:13]=[CH2:14])[CH:6]([CH2:16][CH:17]([CH3:19])[CH3:18])[C:7]([O:9][CH3:10])=[O:8]

Participants

3

Reactant 2

HCID 86646126Methyl 4-allyl-3-hydroxyoctanoateHCID 866461322-Isobutyl-4-pentenal

Product 1

HCID 86646133Methyl 3-hydroxy-2-isobutyl-6-heptenoate

Procedure

The compound of interest (4.5 g, 61%) was obtained as an oil substance (diastereomeric mixture) in the same way as in paragraph (10-a) using 2-isobutyl-4-pentenal.

Sources & evidence

ORD record
ord-b18bf5cc4f884c26a66092a3a23177cc
Source dataset
uspto-grants-2011_05
Patent number
US07947738B2

Linked notes

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