Reaction equation
[CH3:1][C:2]([CH3:4])=O.[CH3:5][CH:6]([CH2:8][C:9]([CH3:11])=[O:10])[CH3:7]>>[CH3:5][CH:6]([CH2:8][C:9]([CH2:11][CH:2]([CH3:4])[CH3:1])=[O:10])[CH3:7]Participants
3
Reactant 2
Product 1
Procedure
Pd was found to be the most effective among metals used for the hydrogenation function of catalysts. The 1% wt. n-Pd/n-ZnCr2O4 gave the most active and selective catalyst for direct synthesis of MIBK from acetone. The highest MIBK selectivity of 72.1% was obtained at 77.3 wt % acetone conversion at 350° C. The total MIBK and DIBK selectivity of 85.6% was obtained at these conditions (Table 5, FIG. 2).
Sources & evidence
- ORD record
- ord-7d3833a6ca634d7c956af11520b78cd4
- Source dataset
- uspto-grants-2011_05
- Patent number
- US07951976B1
Linked notes
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