3,4-Diaminopyridine → 4,4'-Diaminodicyclohexylmethane

Reaction equation

NCC1CCCC(CN)C1.NC1C=CC=C(N)N=1.NC1C=NC=CC=1N.NC1N=C(N)C=CN=1.[NH2:35][C:36]1[CH:37]=[CH:38][C:39]2[C:48]([CH:49]=1)=N[C:46]1[C:41](=[CH:42][CH:43]=[C:44]([NH2:50])[CH:45]=1)[CH:40]=2.NC1C=CC2NC3C(C=2C=1)=CC(N)=CC=3>>[CH2:40]([CH:39]1[CH2:38][CH2:37][CH:36]([NH2:35])[CH2:49][CH2:48]1)[CH:41]1[CH2:42][CH2:43][CH:44]([NH2:50])[CH2:45][CH2:46]1

Participants

Reactant 6

HCID 59183,4-Diaminopyridine

HCID 7099Proflavine

HCID 88612,6-Diaminopyridine

HCID 174061,3-Bis(aminomethyl)cyclohexane

HCID 471089H-carbazole-3,6-diamine

HCID 674312,4-Diaminopyrimidine

Product 1

HCID 156604,4'-Diaminodicyclohexylmethane

Procedure

1,3-bis(aminomethyl)cyclohexane; compounds represented by the formulae (35) to (69); 2,6-diaminopyridine; 3,4-diaminopyridine; 2,4-diaminopyrimidine; 3,6-diaminoacridine; 3,6-diaminocarbazole;

Sources & evidence

ORD record: ord-28f35cbbdd574d059163e0dcac31ad68
Source dataset: uspto-grants-2011_11
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US08057868B2

Reaction notes

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