HuagongsheHuagongshe Chemistry Print Report · For research reference only
3-Chloro-4-methylaniline → (3-Chloro-4-methylphenyl)hydrazine
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | 3-Chloro-4-methylaniline | HCID 7255 | — |
| Reactant | Stannous chloride dihydrate | HCID 61436 | — |
| Reactant | Sodium Nitrite | HCID 23668193 | — |
| Solvent | Hydrochloric Acid | HCID 313 | — |
| Product | (3-Chloro-4-methylphenyl)hydrazine | HCID 292017 | 68,412.602% |
Reaction Steps
The title compound was prepared according to the procedure described in step-1 of Intermediate-61 by using 3-chloro-4-methylaniline (6.0 g, 0.0420 mmol), NaNO2 (8.56 g, 0.050 mmol), SnCl2.2H2O (23.7 g, 0.105 mmol) and conc. HCl (100 mL) to afford 4.5 g of the desired product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US09439890B2 |
| Source dataset | uspto-grants-2016_09 |
| ORD ID | ord-e122a62c34bf4e92874365984c726a1c |
| Source note | uspto-grants-2016_09 |