Reaction equation
[O:1]1[CH2:6]OOOO1.O=O.[C:9]([N:13]=[N:14][C:15]([O:21][OH:22])([CH2:17][CH:18]([CH3:20])[CH3:19])[CH3:16])([CH3:12])([CH3:11])[CH3:10]>>[C:9]([N:13]=[N:14][C:15]([O:21][OH:22])([CH2:17][C:18]([O:1][CH3:6])([CH3:19])[CH3:20])[CH3:16])([CH3:10])([CH3:12])[CH3:11]Participants
4
Conditions
- Temperature
- 0 °C
Procedure
A solution of 60 grams of the t-butylhydrazone of pentoxane (4-methoxy-4-methyl-pentanone-2) in 60 grams of odorless mineral spirits was oxidized by passing oxygen through the solution as in Example II. The oxidation was initiated at 30° C by adding 2 drops of a 50% solution of 2-t-butylazo-2-hydroperoxy-4-methylpentane. The oxidation was 1/2 complete after 50 minutes at 30° C. The temperature was lowered to 20° C. and an additional 1 hour was required before the oxidation was complete. It was then cooled to 0° C. by circulating ice water through the jacket and weighed into a cold poly bottle and stored at -30° C. or below. The yield was 126 g (97% of theory). The solution is not sensitive to shock.
Workup
- customwas initiated at 30° C
- customcomplete after 50 minutes
- customat 30° C
- customstored at -30° C. or below
Sources & evidence
- ORD record
- ord-8d35f088624b472a9a0b7b5fd7042402
- Source dataset
- uspto-grants-1977_03
- Patent number
- US04010152
Linked notes
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