HuagongsheHuagongshe Chemistry Print Report · For research reference only
Thiophenol → phenyl 2,3,4-tri-O-acetyl-1,5-dithio-beta-D-xylopyranoside
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Thiophenol | HCID 7969 | — |
| Reactant | 2,3,4-tri-O-acetyl-5-thio-alpha-xylopyranosyl bromide | HCID 10926314 | — |
| Catalyst | Zinc Oxide | HCID 3007857 | — |
| Product | phenyl 2,3,4-tri-O-acetyl-1,5-dithio-beta-D-xylopyranoside | HCID 14795349 | 32.29% |
Reaction Steps
If the procedure described in Preparation IV is followed starting from 4 g (36.3.10-3 mol) of benzenethiol, 15 g (42.3.10-3 mol) of 2,3,4-tri-O-acetyl-5-thio-α-D-xylopyranosyl bromide and 3 g (36.8.10-3 mol) of zinc oxide (ZnO), 4.5 g (yield: 32.29%) of the expected product are obtained after crystallization from ether.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US05246961 |
| Source dataset | uspto-grants-1993_09 |
| ORD ID | ord-e8f938242b2b48989838b82c5425b8d6 |
| Source note | uspto-grants-1993_09 |