Pentafluoroaniline → 501670-16-2

HRID 601095

Reaction equation

HRID 601095 reaction equation
[C:1]([C:5]1[CH:10]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:8]=[C:7]([CH:15]=NC2C(Br)=CC=CC=2Br)[C:6]=1[OH:25])([CH3:4])([CH3:3])[CH3:2].[F:26][C:27]1[C:33]([F:34])=[C:32]([F:35])[C:31]([F:36])=[C:30]([F:37])[C:28]=1[NH2:29].C(C1C(O)=C(C=C(C(C)(C)C)C=1)C=O)(C)(C)C>>[C:1]([C:5]1[CH:10]=[C:9]([C:11]([CH3:14])([CH3:13])[CH3:12])[CH:8]=[C:7]([CH:15]=[N:29][C:28]2[C:27]([F:26])=[C:33]([F:34])[C:32]([F:35])=[C:31]([F:36])[C:30]=2[F:37])[C:6]=1[OH:25])([CH3:4])([CH3:3])[CH3:2]

Participants

4

Reactant 3

HCID 13040PentafluoroanilineHCID 6880233,5-Di-tert-butylsalicylaldehydeHCID 136346710HCID 136346710, compound

Product 1

HCID 135509894501670-16-2

Procedure

Employing an analogous procedure to that described above for the synthesis of 2,4-bis(tert-butyl)-6-[[(2,6-dibromophenyl)imino]methyl]phenol, 2,3,4,5,6-pentafluoroaniline (0.54 g, 2.9 mmol) was added to 3,5-di-tert-butyl-2-hydroxybenzaldehyde (0.70 g, 2.9 mmol). The product was purified by recrystallisation from hot MeOH and isolated as yellow crystals.

Workup

  1. customThe product was purified by recrystallisation from hot MeOH
  2. customisolated as yellow crystals

Sources & evidence

ORD record
ord-1224c7f7869c44258aeb252783b2e5e7
Source dataset
uspto-grants-2011_03
Patent number
US07902308B2

Linked notes

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