Acetate → alpha-Tocopherol

HRID 602234

Reaction equation

[CH3:1][C:2]1[C:7]2[O:8][C@@:9]([CH2:13][CH2:14][CH2:15][C@@H:16]([CH2:18][CH2:19][CH2:20][C@@H:21]([CH2:23][CH2:24][CH2:25][CH:26]([CH3:28])[CH3:27])[CH3:22])[CH3:17])([CH3:12])[CH2:10][CH2:11][C:6]=2[C:5]([CH3:29])=[C:4]([OH:30])[CH:3]=1.[C:31]([O-])(=O)C.C([O-])(=O)C1C=CC=NC=1.C([O-])(=O)CCC([O-])=O.CC(C)=CCC/C(/C)=C/CC/C(/C)=C/CCC1(C)OC2C=CC(O)=CC=2CC1>>[CH3:31][C:3]1[C:2]([CH3:1])=[C:7]2[C:6]([CH2:11][CH2:10][C@:9]([CH2:13][CH2:14][CH2:15][C@@H:16]([CH2:18][CH2:19][CH2:20][C@@H:21]([CH2:23][CH2:24][CH2:25][CH:26]([CH3:28])[CH3:27])[CH3:22])[CH3:17])([CH3:12])[O:8]2)=[C:5]([CH3:29])[C:4]=1[OH:30]

Participants

Reactant 5

HCID 175Acetate

HCID 937Nicotinate

HCID 160419Succinate

HCID 6857447Beta-Tocopherol

HCID 9929901Tocotrienol

Product 1

HCID 14985alpha-Tocopherol

Procedure

d,l-α-tocopherol; d-β-tocopherol; d,l-β-tocopherol; d-η-tocopherol; and d,l-η-tocopherol (including acetate, hemisuccinate, nicotinate, and succinate-PEG ester forms of each of the foregoing); tocotrienol isomers, and their esters;

Sources & evidence

ORD record: ord-235b492ffcfe47789c47b8c9ed64c0ca
Source dataset: uspto-grants-2011_03
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US07906136B2

Linked notes

Loading…