HCID 53769794, compound → HCID 54157289, compound

HRID 615837

Reaction equation

HRID 615837 reaction equation
[OH:1][CH:2]1[CH2:6][CH2:5][CH:4]([CH2:7][CH:8]=O)[CH2:3]1>[Br-].C1([P+](C2C=CC=CC=2)(C2C=CC=CC=2)CCCC)C=CC=CC=1>[CH2:7]([CH:4]1[CH2:5][CH2:6][CH:2]([OH:1])[CH2:3]1)[CH:8]=[CH:6][CH2:2][CH2:3][CH3:4]

Participants

3

Reactant 1

HCID 53769794HCID 53769794, compound

Product 1

HCID 54157289HCID 54157289, compoundYield 42.7%

Reagents, catalysts & solvents 1

HCID 159628Butyltriphenylphosphonium bromideCatalyst

Procedure

Using the procedure of Example 3, 5 g of 3-hydroxy cyclopentyl-acetaldehyde and 20 g of triphenyl butyl phosphonium bromide were reacted and the product was chromatographed over silica gel. Elution with a 7-3 cyclohexane-ethyl acetate mixture yielded 1.4 g of 3-(2-hexenyl)-cyclopentanol.

Workup

  1. customwere reacted
  2. customthe product was chromatographed over silica gel
  3. washElution with a 7-3 cyclohexane-ethyl acetate mixture

Sources & evidence

ORD record
ord-4cc7bc970b8749cb94668077f684ec93
Source dataset
uspto-grants-1985_02
Patent number
US04501687

Linked notes

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