Acetyl chloride → (1R,S) 1,2,2-trimethyl-1-acetyloxy-3-(2-pentenyl)-cyclopentane

Reaction equation

[CH3:1][C@@:2]1([OH:14])[CH2:6][CH2:5][C@@H:4]([CH2:7][CH:8]=[CH:9][CH2:10][CH3:11])[C:3]1([CH3:13])[CH3:12].[C:15](Cl)(=[O:17])[CH3:16]>>[CH3:1][C@@:2]1([O:14][C:15](=[O:17])[CH3:16])[CH2:6][CH2:5][C@@H:4]([CH2:7][CH:8]=[CH:9][CH2:10][CH3:11])[C:3]1([CH3:13])[CH3:12]

Participants

Reactant 2

HCID 6367Acetyl chloride

HCID 70474476(1R,S) 1,2,2-trimethyl-3-(2-pentenyl)-cyclopentanol

Product 1

HCID 70472830(1R,S) 1,2,2-trimethyl-1-acetyloxy-3-(2-pentenyl)-cyclopentane

Procedure

Using the procedure of Example 15, 2 g of (1R,S) 1,2,2-trimethyl-3-(2-pentenyl)-cyclopentanol and 10 ml of acetyl chloride were reacted to obtain 1.5 g of (1R,S) 1,2,2-trimethyl-1-acetyloxy-3-(2-pentenyl)-cyclopentane.

Workup

customwere reacted

Sources & evidence

ORD record: ord-b6b851ff54c842bd8a1dfea1ddb85357
Source dataset: uspto-grants-1985_02
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04501687

Reaction notes

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