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Germanium chloride → Germane, butyltrichloro-

HRID 615861
Notes
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Reaction equation

HRID 615861 reaction equation
[Cl:1][Ge:2]([CH2:20][CH2:21][CH2:22][CH3:23])([CH2:16][CH2:17][CH2:18][CH3:19])[Ge:3]([CH2:12][CH2:13][CH2:14][CH3:15])([CH2:8][CH2:9][CH2:10][CH3:11])[CH2:4][CH2:5][CH2:6][CH3:7].[Ge:24]([Cl:28])(Cl)([Cl:26])[Cl:25].C([Ge](CCCC)(CCCC)[Ge](CCCC)(CCCC)CCCC)CCC>>[CH2:4]([Ge:24]([Cl:28])([Cl:26])[Cl:25])[CH2:5][CH2:6][CH3:7].[Cl:1][Ge:2]([CH2:16][CH2:17][CH2:18][CH3:19])([CH2:20][CH2:21][CH2:22][CH3:23])[Ge:3]([CH2:8][CH2:9][CH2:10][CH3:11])([CH2:12][CH2:13][CH2:14][CH3:15])[CH2:4][CH2:5][CH2:6][CH3:7]
ParticipantsConditionsProcedureWorkupSources & evidenceReaction notes

Participants

5

Reactant 3

HCID 66226Germanium chlorideHCID 178448182HCID 178448182, compoundHCID 178448183HCID 178448183, compound

Product 2

HCID 78586Germane, butyltrichloro-HCID 178448183HCID 178448183, compound

Conditions

Temperature
200 °C

Procedure

Chloropentabutyldigermane having formula 4 of the formula sheet. A mixture of 5.8 g (27.0 mmoles) of germanium tetrachloride and 12.2 g (27.0 mmoles) of hexabutyldigermane was heated for 6.5 hours at 200° C. in a Carius tube. Fractionated distillation yielded 6.0 g of butyltrichlorogermane and 11.2 g of chloropentabutyldigermane; boiling point 130°-131° C./0.06 mm Hg; nD20 =1.4932.

Workup

  1. distillationFractionated distillation

Sources & evidence

ORD record
ord-57cf3eb3714b4183851211740e74d692
Source dataset
uspto-grants-1985_02
DOI
10.6084/m9.figshare.5104873.v1
Patent number
US04501702

Reaction notes

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On this pageParticipantsConditionsProcedureWorkupSources & evidenceReaction notes