HuagongsheHuagongshe Chemistry Print Report · For research reference only
Potassium Hydroxide → 1-t-Butylazo-1-(t-amylperoxy)cyclohexane
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Potassium Hydroxide | HCID 14797 | — |
| Reactant | tert-Amyl hydroperoxide | HCID 76962 | — |
| Reactant | Cyclohexanol, 1-(2-(1,1-dimethylethyl)diazenyl)- | HCID 94561 | — |
| Reactant | 1-t-Butylazo-1-chlorocyclohexane | HCID 23344784 | — |
| Product | 1-t-Butylazo-1-(t-amylperoxy)cyclohexane | HCID 20367904 | — |
Reaction Steps
The 1-t-butylazo-1-(t-amylperoxy)cyclohexane was prepared in 85% crude yield from 7.5 grams (.037 moles) of 1-t-butylazo-1-chlorocyclohexane, 6.0 grams (.052 moles) of 90% t-amyl hydroperoxide and 9.1 grams (.0407 moles) of 25% potassium hydroxide solution. The procedure was the same as that described in Example XX. The infrared spectrum of the product indicated there was a small amount of 1-t-butylazo-1-hydroxycyclohexane present in the product.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04075199 |
| Source dataset | uspto-grants-1978_02 |
| ORD ID | ord-5ff53a4a30ca43f7a2b3fd462144ebf0 |
| Source note | uspto-grants-1978_02 |