Nitric Acid → HCID 21421760, compound

HRID 622313

Reaction equation

HRID 622313 reaction equation
[C:1]1([CH:7]([N:9]2[C:13]([C:14]([O:16][CH2:17][CH3:18])=[O:15])=[CH:12][N:11]=[CH:10]2)[CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1.[N+:19]([O-:22])([OH:21])=[O:20]>CC(=O)C>[N+:19]([O-:22])([OH:21])=[O:20].[C:1]1([CH:7]([N:9]2[C:13]([C:14]([O:16][CH2:17][CH3:18])=[O:15])=[CH:12][N:11]=[CH:10]2)[CH3:8])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

4

Reactant 2

HCID 944Nitric AcidHCID 36339Ethnor

Product 1

HCID 21421760HCID 21421760, compound

Reagents, catalysts & solvents 1

HCID 180AcetoneSolvent

Procedure

To a solution of 12.2 parts of ethyl 1-(1-phenylethyl)-1H-imidazole-5-carboxylate in 160 parts of 2-propanone were added 5 parts of a nitric acid solution 65%. The product solidifies on scratching, yielding 14 parts of ethyl 1-(1-phenylethyl)-1H-imidazole-5-carboxylate mononitrate; mp. 138°-139° C. (compound 1.146).

Sources & evidence

ORD record
ord-fd17da97d4d7482c817be3ac7ed7d2a0
Source dataset
uspto-grants-1988_09
Patent number
US04770689

Linked notes

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