Thiophenol → Diphenyl sulfide

HRID 623238

Reaction equation

HRID 623238 reaction equation
[C:1]1([SH:7])[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1>C1(C)C=CC=CC=1>[C:1]1([S:7][C:1]2[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=2)[CH:6]=[CH:5][CH:4]=[CH:3][CH:2]=1

Participants

3

Reactant 1

HCID 7969Thiophenol

Product 1

HCID 8766Diphenyl sulfide

Reagents, catalysts & solvents 1

HCID 1140TolueneSolvent

Procedure

A mixture of bis(dineophyl-orthotrifluoromethylphenyltin)oxide (6.0 g, 5.6 mmol) prepared in Example 6, thiophenol (1.2 g, 11.2 mmol) and toluene (40 g) was treated with the procedure described in Example 7. The product was recrystallized from n-hexane to obtain 5.2 g of dineophylorthotrifluoromethylphenyltin phenylsulfide as a white solid.

Workup

  1. additionwas treated with the procedure
  2. customThe product was recrystallized from n-hexane

Sources & evidence

ORD record
ord-7087eac787814b4481a45eda5fa3f06b
Source dataset
uspto-grants-1988_09
Patent number
US04774235

Linked notes

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