1-Bromododecane → 1-Pentadecene

HRID 625900

Reaction equation

[CH2:1](Br)[CH2:2][CH2:3][CH2:4][CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH3:12].C(O[CH2:18][CH:19]=[CH2:20])(=O)C>>[CH2:12]=[CH:11][CH2:10][CH2:9][CH2:8][CH2:7][CH2:6][CH2:5][CH2:4][CH2:3][CH2:2][CH2:1][CH2:18][CH2:19][CH3:20]

Participants

Reactant 2

HCID 89191-Bromododecane

HCID 11584Allyl acetate

Product 1

HCID 259131-PentadeceneYield 32%

Procedure

n-dodecyl bromide was converted analogously to example 1 to its Grignard compound and the latter was reacted with allyl acetate in the manner described. 1-Pentadecene was obtained in 32% yield.

Sources & evidence

ORD record: ord-63c0006c2b7f4ff5b7cde3d0d1bf68f7
Source dataset: uspto-grants-2016_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US09309188B2

Linked notes

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