Benzene → HCID 24972838, compound

HRID 638656

Reaction equation

HRID 638656 reaction equation
[C:1]([O:11][CH2:12][CH:13]=[CH2:14])(=[O:10])/[CH:2]=[CH:3]\[C:4]([O:6][CH2:7][CH:8]=[CH2:9])=[O:5].CCC(OO)=[O:18].C1C=CC=CC=1>>[C:4]([O:6][CH2:7][CH:8]=[CH2:9])(=[O:5])/[CH:3]=[CH:2]\[C:1]([O:11][CH2:12][CH:13]1[O:18][CH2:14]1)=[O:10]

Participants

4

Reactant 3

HCID 241BenzeneHCID 65136Perpropionic acidHCID 5354266Diallyl maleate2×

Product 1

HCID 24972838HCID 24972838, compound

Procedure

9.8 kg (50 mol) of diallyl maleate were reacted with 28.9 kg of a 21.8% strength solution of perpropionic acid in benzene (70 mol) at a reaction temperature of 60° C. in a manner analogous to that described in Example 1. After a reaction time of 8.5 hours, the percarboxylic acid conversion was 97.2%. The conversion of diallyl maleate was 88.3%. Allyl glycidyl maleate was formed with a selectivity of 45.8% and diglycidyl maleate was formed with a selectivity of 44.7%, in each case based on the diallyl maleate reacted.

Workup

  1. customAfter a reaction time of 8.5 hours

Sources & evidence

ORD record
ord-b896975d101b425895e9a9b601cd0ea7
Source dataset
uspto-grants-1985_12
Patent number
US04562274

Linked notes

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