Benzene → HCID 22034851, compound

HRID 638657

Reaction equation

HRID 638657 reaction equation
[C:1]([O:11][CH2:12][CH:13]=[CH2:14])(=[O:10])/[CH:2]=[CH:3]/[C:4]([O:6][CH2:7][CH:8]=[CH2:9])=[O:5].CCC(OO)=[O:18].C1C=CC=CC=1>>[C:4]([O:6][CH2:7][CH:8]=[CH2:9])(=[O:5])/[CH:3]=[CH:2]/[C:1]([O:11][CH2:12][CH:13]1[O:18][CH2:14]1)=[O:10]

Participants

4

Reactant 3

HCID 241BenzeneHCID 65136Perpropionic acidHCID 5355330Diallyl fumarate2×

Product 1

HCID 22034851HCID 22034851, compound

Procedure

9.8 kg (50 mol) of diallyl fumarate were reacted with 26.18 kg of a 22% strength solution of perpropionic acid in benzene (64 mol) at 60° C. in a manner analogous to that described in Example 1. After a reaction time of 6.8 hours, a percarboxylic acid conversion of 96.8% resulted. The conversion of diallyl fumarate was 90%. Allyl glycidyl fumarate was formed with a selectivity of 46.2% and diglycidyl fumarate was formed with a selectivity of 42.3%, in each case based on the diallyl fumarate reacted.

Workup

  1. customAfter a reaction time of 6.8 hours, a percarboxylic acid conversion of 96.8% resulted

Sources & evidence

ORD record
ord-a2318753c1474807a85d88147d159cd1
Source dataset
uspto-grants-1985_12
Patent number
US04562274

Linked notes

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