Tetradecyl isocyanate → N-(D-Glucopyranosyl)-N-dodecyl-N'-tetradecylurea

Reaction equation

[CH:1]1(CCCCCCCCCCCCN)[O:9][C@H:8]([CH2:10][OH:11])[C@@H:6]([OH:7])[C@H:4]([OH:5])[C@H:2]1[OH:3].[CH2:25]([N:39]=[C:40]=[O:41])[CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH3:38]>>[CH:1]1([N:39]([CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH3:36])[C:40]([NH:39][CH2:25][CH2:26][CH2:27][CH2:28][CH2:29][CH2:30][CH2:31][CH2:32][CH2:33][CH2:34][CH2:35][CH2:36][CH2:37][CH3:38])=[O:41])[O:9][C@H:8]([CH2:10][OH:11])[C@@H:6]([OH:7])[C@H:4]([OH:5])[C@H:2]1[OH:3]

Participants

Reactant 2

HCID 3485710Tetradecyl isocyanate

HCID 86742093N-(D-Glucopyranosyl)dodecylamine

Product 1

HCID 53781110N-(D-Glucopyranosyl)-N-dodecyl-N'-tetradecylurea

Procedure

The preparation is analogous to Example 42, starting from 7.0 g of the compound of Example 1 and 4.8 g of tetradecyl isocyanate.

Sources & evidence

ORD record: ord-a77aea2b364f4d9597acf582491511b7
Source dataset: uspto-grants-1988_04
DOI: 10.6084/m9.figshare.5104873.v1
Patent number: US04737488

Reaction notes

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