5-Bromo-2-furanecarboxylic acid → 5-(2-Methyltetradecyloxy)-2-furancarboxylic acid

HRID 649227

Reaction equation

HRID 649227 reaction equation
[CH3:1][CH:2]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[CH2:3][OH:4].C(O)CCCCCCCCC/C=C\CC.Br[C:33]1[O:37][C:36]([C:38]([OH:40])=[O:39])=[CH:35][CH:34]=1.ClC1OC(C(O)=O)=CC=1>>[CH3:1][CH:2]([CH2:5][CH2:6][CH2:7][CH2:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH3:16])[CH2:3][O:4][C:33]1[O:37][C:36]([C:38]([OH:40])=[O:39])=[CH:35][CH:34]=1

Participants

5

Reactant 4

HCID 685115-Bromo-2-furanecarboxylic acidHCID 2348535-Chlorofuran-2-carboxylic acidHCID 1712010Cis-11-tetradecenolHCID 140296512-Methyltetradecan-1-ol

Product 1

HCID 136560035-(2-Methyltetradecyloxy)-2-furancarboxylic acid

Procedure

In the procedure of Example 4(A), 2-methyltetradecanol was substituted for cis-11-tetradecenol and 5-bromo-2-furoic acid substituted for 5-chloro-2-furoic acid to yield 5-(2-methyltetradecyloxy)-2-furancarboxylic acid, M.P. 88°-90° C.

Sources & evidence

ORD record
ord-e4679fcace834da3bd0a6b667a4a0a5e
Source dataset
uspto-grants-1988_04
Patent number
US04738984

Linked notes

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