Dimethyl Carbonate → Diphenyl carbonate
Reaction equation
ClC(O[C:5]1[CH:10]=[CH:9][CH:8]=[CH:7]C=1)=O.[C:11](=[O:16])([O:14][CH3:15])[O:12][CH3:13]>CC1C(CN2CCC(N3CCC(N4C(=O)NC5C4=CC=CC=5)CC3)CC2)=CC=CC=1>[C:11](=[O:16])([O:14][C:15]1[CH:7]=[CH:8][CH:9]=[CH:10][CH:5]=1)[O:12][C:13]1[CH:5]=[CH:10][CH:9]=[CH:8][CH:7]=1Participants
4
Reactant 2
Product 1
Reagents, catalysts & solvents 1
Conditions
- Temperature
- 150 °C
Procedure
A mixture of 7.83 g (0.05 mole) of phenyl chloroformate, 2.48 g (0.0275 mole) of dimethyl carbonate, and 0.85 g of TBPB was heated at 150° C. under a reflux condenser for 4 hours when all gas evolution had ceased. Distillation of the reaction mixture gave 5.25 g (98 percent yield based on chloroformate) of diphenyl carbonate.
Workup
- distillationDistillation of the reaction mixture
Sources & evidence
- ORD record
- ord-bc5acf575b5c44f6967b29f0bee19519
- Source dataset
- uspto-grants-1986_09
- Patent number
- US04612386
Reaction notes
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