1-Methyl-4-Prop-1-En-2-Ylcyclohexene → N-CBZ-S-(1-(4-methylcyclohex-3-enyl)isopropyl)-L-cysteine methyl ester

HRID 653388

Reaction equation

HRID 653388 reaction equation
[CH3:1][O:2][C:3](=[O:18])[C@H:4]([CH2:16][SH:17])[NH:5][C:6]([O:8][CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)=[O:7].[CH3:19][C:20]1[CH2:25][CH2:24][CH:23]([C:26]([CH3:28])=[CH2:27])[CH2:22][CH:21]=1>CCOCC>[CH3:1][O:2][C:3](=[O:18])[C@H:4]([CH2:16][S:17][C:26]([CH:23]1[CH2:24][CH2:25][C:20]([CH3:19])=[CH:21][CH2:22]1)([CH3:28])[CH3:27])[NH:5][C:6]([O:8][CH2:9][C:10]1[CH:15]=[CH:14][CH:13]=[CH:12][CH:11]=1)=[O:7]

Participants

4

Reactant 2

HCID 223111-Methyl-4-Prop-1-En-2-YlcyclohexeneHCID 11391550Methyl (2R)-2-{[(benzyloxy)carbonyl]amino}-3-sulfanylpropanoate

Product 1

HCID 131715037N-CBZ-S-(1-(4-methylcyclohex-3-enyl)isopropyl)-L-cysteine methyl ester

Reagents, catalysts & solvents 1

HCID 3283Diethyl EtherSolvent

Procedure

The ether is prepared from N-CBZ-L-cysteine methyl ester and α-limonene in a manner similar to that described in Example 1B. The product can be characterized by NMR spectroscopy.

Sources & evidence

ORD record
ord-1a9b5d3ea53e4527a40b117876aec43d
Source dataset
uspto-grants-1987_06
Patent number
US04676989

Linked notes

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