Thiodiglycol → 1-Bromooctadecane

HRID 654833

Reaction equation

HRID 654833 reaction equation
[CH2:1]([OH:7])[CH2:2][S:3][CH2:4][CH2:5][OH:6].[Br:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH3:24]>C(O)COCCO>[Br:8][CH2:9][CH2:10][CH2:11][CH2:12][CH2:13][CH2:14][CH2:15][CH2:16][CH2:17][CH2:18][CH2:19][CH2:20][CH2:21][CH2:22][CH2:23][CH2:24][CH2:4][CH3:5].[CH2:24]([O:7][CH2:1][CH2:2][S:3][CH2:4][CH2:5][OH:6])[CH2:23][CH2:22][CH2:21][CH2:20][CH2:19][CH2:18][CH2:17][CH2:16][CH2:15][CH2:14][CH2:13][CH2:12][CH2:11][CH2:10][CH3:9]

Participants

5

Reactant 2

HCID 5447ThiodiglycolHCID 82131-Bromohexadecane

Product 2

HCID 82181-BromooctadecaneHCID 157245082-(2-Hexadecyloxyethylthio)ethanol

Reagents, catalysts & solvents 1

HCID 8117Diethylene GlycolSolvent

Procedure

Following the procedure described in preparation 1, but using thiodiethylene glycol and 1-bromohexadecane, instead of diethylene glycol and 1-bromooctadecane, respectively, the title compound was obtained in a similar yield.

Workup

  1. customdescribed in preparation 1

Sources & evidence

ORD record
ord-3e8681154ac9488880e66f27121d7a72
Source dataset
uspto-grants-1992_07
Patent number
US05134151

Linked notes

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