HuagongsheHuagongshe Chemistry Print Report · For research reference only
Allyl chloride → Silane, chloro(3-chloropropyl)dimethyl-
Participants
| Role | Name | HCID | Charge |
|---|---|---|---|
| Reactant | Allyl chloride | HCID 7850 | — |
| Reactant | Triethylsilane | HCID 12052 | — |
| Reactant | Chlorodimethylsilane | HCID 66108 | — |
| Product | Silane, chloro(3-chloropropyl)dimethyl- | HCID 82765 | 42.5% |
| Product | (3-Chloropropyl)(triethyl)silane | HCID 12566784 | 4.8% |
Reaction Steps
In a 100 ml apparatus, there were combined 7.1 g (0.075 mol) of Me2SiHCl, 8.7 g (0.075 mol) of Et3SiH and 5.7 g (0.075 mol) of allyl chloride. Pt catalyst solution was added (0.05 ml) at 34° C. Gentle heating caused a smooth exothermic reaction to 92° over 36 min. Vacuum distillation yielded 42.5% of Me2SiClCH2CH2CH2Cl and 4.8% of Et3SiCH2CH2CH2Cl. This example shows that Et3SiH at the equimolar level is an effective promoter for the reaction between Me2SiHCl and allyl chloride.
Provenance & Evidence
| DOI | 10.6084/m9.figshare.5104873.v1 |
|---|---|
| Patent number | US04614812 |
| Source dataset | uspto-grants-1986_09 |
| ORD ID | ord-ea010ac8c17a469998fda743e4cb84e6 |
| Source note | uspto-grants-1986_09 |