2-Benzyl-2-(dimethylamino)-1-(4-(morpholin-4-yl)phenyl)butan-1-one → 2-Hydroxy-2-methyl-1-phenylpropan-1-one

HRID 655082

Reaction equation

HRID 655082 reaction equation
[CH3:1][C:2]([OH:16])([C:4]([C:6]1[CH:11]=[CH:10][C:9](OCCO)=[CH:8][CH:7]=1)=[O:5])[CH3:3].CC(N1CCOCC1)(C(C1C=CC(SC)=CC=1)=O)C.CCC(N(C)C)(C(C1C=CC(N2CCOCC2)=CC=1)=O)CC1C=CC=CC=1.C1C=CC(C(C(OCCOCCOC(C(C2C=CC=CC=2)=O)=O)=O)=O)=CC=1>C1C=C[CH]C=1.C1C=C[CH]C=1.C1C=CN([C]2C(F)=C=C(F)C=C2)C=1.C1C=CN([C]2C(F)=C=C(F)C=C2)C=1.[Ti]>[OH:16][C:2]([CH3:3])([CH3:1])[C:4]([C:6]1[CH:11]=[CH:10][CH:9]=[CH:8][CH:7]=1)=[O:5]

Participants

6

Reactant 4

HCID 861712-Benzyl-2-(dimethylamino)-1-(4-(morpholin-4-yl)phenyl)butan-1-oneHCID 862662-Hydroxy-1-(4-(hydroxyethoxy)phenyl)-2-methyl-1-propanoneHCID 923872-Methyl-1-(4-(methylthio)phenyl)-2-morpholino-1-propanoneHCID 60004985Benzeneacetic acid, alpha-oxo-, 1,1'-(oxydi-2,1-ethanediyl) ester

Product 1

HCID 819842-Hydroxy-2-methyl-1-phenylpropan-1-one

Reagents, catalysts & solvents 1

HCID 178505935HCID 178505935, compoundCatalyst

Procedure

Other examples are Irgacure 2959, Irgacure 127, Irgacure 907, Irgacure 369, Irgacure 379, Darocur TPO, Irgacure 819, Irgacure 784, Irgacure OXE01, Irgacure OXE02, and Irgacure 754 (all are manufactured by Ciba Specialty Chemicals).

Sources & evidence

ORD record
ord-4848b3a291ef4645b861f485a2887eb0
Source dataset
uspto-grants-2011_12
Patent number
US08070968B2

Linked notes

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