Dimethyladipate → Disodium adipate

HRID 65824

Reaction equation

HRID 65824 reaction equation
[C:1]([O:11]C)(=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([O:8]C)=[O:7].[OH-].[Na+:14]>C(#N)C>[C:1]([O-:11])(=[O:10])[CH2:2][CH2:3][CH2:4][CH2:5][C:6]([O-:8])=[O:7].[Na+:14].[Na+:14]

Participants

4

Reactant 2

HCID 12329DimethyladipateHCID 14798Sodium Hydroxide

Product 1

HCID 24073Disodium adipate

Reagents, catalysts & solvents 1

HCID 6342AcetonitrileSolvent

Procedure

17.4 g. (0.1 mole) of dimethyl adipate were dissolved in 100 mls. of acetonitrile and heated to 70° C. 8.2 g. (0.2 mole) of 97% pure sodium hydroxide were added to the reaction mixture as a fine powder (50 mesh). The reaction mixture was stirred at reflux temperature for 18 hours. The resulting solution was filtered hot and the solids were air dried to yield disodium adipate as the reaction product.

Workup

  1. temperatureat reflux temperature for 18 hours
  2. filtrationThe resulting solution was filtered hot
  3. customdried

Sources & evidence

ORD record
ord-af3c1eef92454c249d5f397014b710cf
Source dataset
uspto-grants-1978_12
Patent number
US04129520

Linked notes

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